Isaac Scientific Publishing
Modern Organic Chemistry Research
MOCR > Volume 2, Number 3, August 2017

Synthesis of Adamantyl-Containing Compounds - Structure Elements of Rotaxanes and Supramolecular Polymers

Download PDF  (343.3 KB)PP. 124-129,  Pub. Date:July 4, 2017
DOI: 10.22606/mocr.2017.23005

Author(s)
Gennady M. Butov, Vladimir Burmistrov, Karim R. Saad
Affiliation(s)
Volzhsky Polytechnic Institute (branch) Volgograd State Technical University, Department of Chemistry, Technology and Equipment of Chemical Production, 42a Engels st., Volzhsky, Russia;
Volzhsky Polytechnic Institute (branch) Volgograd State Technical University, Department of Chemistry, Technology and Equipment of Chemical Production, 42a Engels st., Volzhsky, Russia;
Volzhsky Polytechnic Institute (branch) Volgograd State Technical University, Department of Chemistry, Technology and Equipment of Chemical Production, 42a Engels st., Volzhsky, Russia
Abstract
This manuscript deals with the synthesis of various Adamantane derivatives as objects of supramolecular chemistry, in particular, supramolecular Cyclodextrine polymers (SCP) and Rotaxanes. One of the structural elements of the SCP and Rotaxanes are linear molecules modified by the end-blockers. A considerable volume of adamantyl group allows Adamantane derivatives to create locking groups in Rotaxanes, and a high affinity for β-Cyclodextrine to create supramolecularpolymers.
Keywords
Adamantane, Cyclodextrine, Isocyanate, supramolecular polymer, urea.
References
  • [1]  F.M. Raymo and J.F. Stoddart, Chem. Rev. 1999, 99, 1643-1666.
  • [2]  A. Harada, A. Hashidzume, H. Yamaguchi and Y. Takashima, Chem. Rev. 2009, 109, 5974-6023.
  • [3]  T. Vermonden, V.D. Manakken, Biomacromolecules 2009, 10(42), 3157-3175.
  • [4]  M. Munteanu, S. Choi, H. Ritter, J. Incl. Phenom. Macrocycl. Chem. 2008, 62, 197-202.
  • [5]  M. Sun, H. Zhang, X. Hu, B. Liu and Y. Liu, Chin. J. Chem. 2014, 32(8), 771-776.
  • [6]  F.Szillat, B.V.K.J. Schmidt, A. Hubert, C. Barner-Kowollikand, H. Ritter, Macromol. Rapid Commun. 2014, 35(14), 1293-1300.
  • [7]  C. Zou, M. Liang, X. Chen and X. Yan, J. Appl. Polym. Sci. 2013, 131(9), 40197.
  • [8]  S. Liu, Y. Wang, J.Cai, L. Ren,L. Wang and Y. Wang, Polym. Int. 2014, DOI: 10.1002/pi.4732.
  • [9]  A. El Fagui, V.Wintgens, C.Gaillet, P.Dubot and C.Amiel, Macromol. Chem. Phys. 2014, 215(6), 555-565.
  • [10]  C. Fleischmann and H. Ritter, Macromol. Rapid Commun. 2013, 34(13), 1085-1089.
  • [11]  S.H. Hwang, H.J. Tsai, J.Y. Liu, C. Morisseau, B.D. Hammock, J. Med. Chem. 2007, 50, 3825-3840.
  • [12]  V. Burmistrov, C. Morisseau, K.S.S. Lee, D.S. Shihadih, T.R. Harris, G.M. Butov, B.D. Hammock, Bioorg. Med. Chem. Lett. 2014, 24, 2193-2197.
  • [13]  V.V. Burmistrov, G.M. Butov, Journal of VSTU 2013, 11(19), 25-29.
  • [14]  G.M. Butov,V.V. Burmistrov, Journal of VSTU 2012,5(9), 62-66.
  • [15]  Y.V. Popov, V.M. Mohov, O.Y. Zimina, Journal of VSTU 2008, 1(5), 49-52.
  • [16]  G.M. Butov, V.V. Burmistrov, K.R. Saad, J. Chem. Chem. Eng. 2012, 6, 774-777.
  • [17]  P.D. Skelly, W.J. Ray, J.W. Timberlake, J. Org. Chem. 1985, 50(2), 4282–4283.
Copyright © 2017 Isaac Scientific Publishing Co. All rights reserved.