Modern Organic Chemistry Research

Cation-Anionic Association of Organic Dyes in Aqueous Solutions: Structure and Properties of Associates

Download PDF (457.6 KB) PP. 195 - 203 Pub. Date: November 1, 2017

DOI: 10.22606/mocr.2017.24006

Author(s)

Serghey A. Shapovalov^*
Institute of Chemistry, V. N. Karazin Kharkiv National University, Ukraine

Abstract

Using the experimental and quantum chemical methods, the ionic association of dyes (cyanines, sulfonephthaleins) in aqueous solutions was systematically studied. The main regularities of association processes are revealed. The attention is focused on properties of cation-anionic associates of stoichiometric composition Ct+HAn– and (Ct+)2An2–. The equilibrium association constants are spectrophotometrically determined. The enthalpies of formation of ions and associates were simulated by semiempirical AM1, PM3 methods. The most probable structures of associates are discussed.

Keywords

Dyes, cyanines, association, spectrophotometry, association constant, enthalpy of formation, cation-anionic associates, semiempirical methods, solution.

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